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需要配置两个文档：php.ini（C:\xampp\php）和sendmail.ini（C:\xampp\sendmail）
一、php.ini
[mail function]
; XAMPP: Comment out this if you want to work with an SMTP Server like Mercury
;SMTP = smtp.163.com
;smtp_port = 25
;sendmail_from=
sendmail_path = "C:\xampp\sendmail\sendmail.exe -t" (只需要配置这行，其它都注释掉,sendmail.exe的路径)
; For Win32 only.
; http://php.net/sendmail-from
;sendmail_from = postmaster@localhost
;sendmail_from =
; XAMPP IMPORTANT NOTE (1): If XAMPP is installed in a base directory with spaces (e.g. c:\program filesC:\xampp) fakemail and mailtodisk do not work correctly.
; XAMPP IMPORTANT NOTE (2): In this case please copy the sendmail or mailtodisk folder in your root folder (e.g. C:\sendmail) and use this for sendmail_path.
; XAMPP: Comment out this if you want to work with fakemail for forwarding to your mailbox (sendmail.exe in the sendmail folder)
;sendmail_path = "\"C:\xampp\sendmail\sendmail.exe\" -t"
; XAMPP: Comment out this if you want to work with mailToDisk, It writes all mails in the C:\xampp\mailoutput folder
;sendmail_path="C:\xampp\mailtodisk\mailtodisk.exe"
; Force the addition of the specified parameters to be passed as extra parameters
; to the sendmail binary. These parameters will always replace the value of
; the 5th parameter to mail(), even in safe mode.
;mail.force_extra_parameters =
; Add X-PHP-Originating-Script: that will include uid of the script followed by the filename
mail.add_x_header=Off
; Log all mail() calls including the full path of the script, line #, to address and headers
mail.log = "C:\xampp\php\logs\php_mail.log"
二、sendmail.ini
smtp_server=smtp. 126.com
smtp_port=25
smtp_ssl=auto
default_domain= 126.com
auth_username=yourmail@ 126.com（你的邮箱）
auth_password= password(你的邮箱密码)
force_sender=yourmail@ 126.com
只需要配置这几项，上面的 126可以换成你用的邮箱例如163，sina等。注意把邮箱的smtp功能开启，到邮箱设置里设置。
三、测试
配置后，保存，重启服务器
<?php
$to = 'xxxxx@126.com';
$subject = 'xxxx';
$message = 'xxxx';
if(mail($to, $subject, $message))
{
echo "<br /> Success 0 <br />";
} else{
echo "<br /> fail <br />";
}
?>
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